Physical Chemistry (Fall 2017)

Physical Chemistry (Fall 2017)

Prof. Robert Field via MIT OpenCourseWare Direct link

15. Non-Degenerate Perturbation Theory I

15 of 36

15 of 36

15. Non-Degenerate Perturbation Theory I

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Classroom Contents

Physical Chemistry (Fall 2017)

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  1. 1 1. Quantum Mechanics—Historical Background, Photoelectric Effect, Compton Scattering
  2. 2 2. Wave Nature of the Electron and the Internal Structure of an Atom
  3. 3 3. Two-Slit Experiment; Quantum Weirdness
  4. 4 4. Classical Wave Equation and Separation of Variables
  5. 5 5. Quantum Mechanics: Free Particle and Particle in 1D Box
  6. 6 6. 3-D Box and QM Separation of Variables
  7. 7 7. Classical Mechanical Harmonic Oscillator
  8. 8 8. Quantum Mechanical Harmonic Oscillator
  9. 9 9. The Harmonic Oscillator: Creation and Annihilation Operators
  10. 10 10. The Time-Dependent Schrödinger Equation
  11. 11 11. Wavepacket Dynamics for Harmonic Oscillator and PIB
  12. 12 12. Catch Up and Review & Postulates
  13. 13 13. From Hij Integrals to H Matrices I
  14. 14 14. From Hij Integrals to H Matrices II
  15. 15 15. Non-Degenerate Perturbation Theory I
  16. 16 16. Non-Degenerate Perturbation Theory II: HO using a,a†
  17. 17 17. Rigid Rotor I; Orbital Angular Momentum
  18. 18 18. Rigid Rotor II. Derivation by Commutation Rules
  19. 19 19. Spectroscopy: Probing Molecules with Light
  20. 20 20. Hydrogen Atom I
  21. 21 21. Hydrogen Atom II; Rydberg States
  22. 22 22. Helium Atom
  23. 23 23. Many-Electron Atoms
  24. 24 24. Molecular Orbital Theory I; Variational Principle and Matrix Mechanics
  25. 25 25. Molecular Orbital Theory II; H2+, A2, AB Diatomics
  26. 26 26. Qualitative MO Theory: Hückel
  27. 27 27. Non-Degenerate Perturbation Theory III
  28. 28 28. Modern Electronic Structure Theory: Basis Sets
  29. 29 29. Modern Electronic Structure Theory: Electronic Correlation
  30. 30 30. Time-Dependent Perturbation Theory I: H is Time-Independent, Zewail Wavepacket.
  31. 31 31. Time-Dependent Perturbation Theory II: H is Time-Dependent: Two-Level Problem
  32. 32 32. Intermolecular Interactions by Non-Degenerate Perturbation Theory
  33. 33 33. Electronic Spectroscopy: Franck-Condon
  34. 34 34. Electronic Spectroscopy and Photochemistry
  35. 35 35. Delta-Functions, Eigen-Functions of X, Discrete Variable Representation
  36. 36 36. Time Dependence of Two-Level Systems: Density Matrix, Rotating Wave Approximation

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