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Indian Institute of Technology Guwahati

Advanced Thermodynamics

Indian Institute of Technology Guwahati and NPTEL via Swayam

Overview

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In any chemical process, often one encounter interaction between phases where transfer of species takes place from one phase to other. That is there exist several situations of vapor-liquid, liquid-liquid, vapor-liquid-liquid, solid-liquid equilibria in chemical engineering processes. Often these situations are dealt with assumption of ideal behavior and binary systems but in reality non-ideality and multicomponent mixtures exists and accordingly one has to deal with such situations. This course offers step-by-step understanding of required thermodynamic properties to handle such equilibrium cases and explore possible ways of solving problems associated with non-ideality in VLE, LLE, VLLE and SLE for multicomponent mixtures. INTENDED AUDIENCE : Chemical Engineering, Biotechnology, Petroleum Engineering, Polymer Engineering and Food Engineering PREREQUISITES : UG Level Thermodynamics CourseINDUSTRY SUPPORT : Oil and Gas Industries, Chemical Industries, Polymer Industries, Biochemical Industries

Syllabus

Week 1:Introduction of Phase Equilibria
Week 2: Estimation of Thermodynamic Properties
Week 3: Potential Energy Functions and Intermolecular Forces
Week 4: Molecular Theory of Corresponding States
Week 5:Intermolecular Interactions and E.o.S
Week 6:Gaseous Mixtures and Fugacity
Week 7: Liquid Mixtures and Fugacity
Week 8: Models for Activity Coefficients using Excess Gibbs Energy
Week 9: Vapor – Liquid Equilibria of Multicomponent Non-Ideal Systems
Week 10: Liquid – Liquid Equilibria of Multicomponent Non-Ideal Systems
Week 11: Vapor – Liquid – Liquid Equilibria of Multicomponent Non-Ideal Systems
Week 12: Solid – Liquid Equilibria of Non-Ideal Systems

Taught by

Prof. Nanda Kishore

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