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Indian Institute of Technology Guwahati

Advanced Thermodynamics

Indian Institute of Technology Guwahati and NPTEL via Swayam

Overview

In any chemical process, often one encounter interaction between phases where transfer of species takes place from one phase to other. That is there exist several situations of vapor-liquid, liquid-liquid, vapor-liquid-liquid, solid-liquid equilibria in chemical engineering processes. Often these situations are dealt with assumption of ideal behavior and binary systems but in reality non-ideality and multicomponent mixtures exists and accordingly one has to deal with such situations. This course offers step-by-step understanding of required thermodynamic properties to handle such equilibrium cases and explore possible ways of solving problems associated with non-ideality in VLE, LLE, VLLE and SLE for multicomponent mixtures. INTENDED AUDIENCE : Chemical Engineering, Biotechnology, Petroleum Engineering, Polymer Engineering and Food Engineering PREREQUISITES : UG Level Thermodynamics CourseINDUSTRY SUPPORT : Oil and Gas Industries, Chemical Industries, Polymer Industries, Biochemical Industries

Syllabus

COURSE LAYOUT

Week 1:Introduction of Phase Equilibria
Week 2: Estimation of Thermodynamic Properties
Week 3: Potential Energy Functions and Intermolecular Forces
Week 4: Molecular Theory of Corresponding States
Week 5:Intermolecular Interactions and E.o.S
Week 6:Gaseous Mixtures and Fugacity
Week 7: Liquid Mixtures and Fugacity
Week 8: Models for Activity Coefficients using Excess Gibbs Energy
Week 9: Vapor – Liquid Equilibria of Multicomponent Non-Ideal Systems
Week 10: Liquid – Liquid Equilibria of Multicomponent Non-Ideal Systems
Week 11: Vapor – Liquid – Liquid Equilibria of Multicomponent Non-Ideal Systems
Week 12: Solid – Liquid Equilibria of Non-Ideal Systems

Taught by

Prof. Nanda Kishore

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